SUPERPOSITION
OF DIFFUSION AND CHEMICAL REACTION CONTROLLED LIMITING CURRENTS - APPLICATION TO CO2 CORROSION |
by |
Srdjan Nesic¤, B.F.M. Pots#, John Postlethwaite* and Nicolas Thevenot¤ |
Abstract |
It was
observed experimentally that a chemical reaction limiting current can
be affected by flow. In the present study a new more general expression
than the one found in literature was derived for the superposition of
the diffusion and chemical reaction controlled limiting currents . It
was found that their interaction in the case of CO 2 corrosion is significant
at temperatures lower than 40°C and velocities higher than 1 m/s when
the mass transfer layer is of the similar thickness as the reaction layer.
|