A Mechanistic Model for Carbon Dioxide Corrosion
of Mild Steel in the Presence of Protective Iron
Carbonate Films—Part 1: Theory and Verification |
by |
M. Nordsveen,* S. Nes˘ic´,‡,** R. Nyborg,*** and A. Stangeland**** |
Abstract |
A mechanistic model of uniform carbon dioxide (CO2) corrosion
is presented that covers the following: electrochemical
reactions at the steel surface, diffusion of species between
the metal surface and the bulk including diffusion through
porous surface films, migration due to establishment of potential
gradients, and homogenous chemical reactions including
precipitation of surface films. The model can predict the
corrosion rate as well as the concentration and flux profiles
for all species involved. Comparisons with laboratory experiments
have revealed the strengths of the model such as its
ability to assist in understanding complex processes taking
place during corrosion in the presence of surface films.
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